Radical chemistry in polymer science: an overview and recent advances

• Zixiao Wang,
• Feichen Cui,
• Yang Sui and
• Jiajun Yan

Beilstein J. Org. Chem. 2023, 19, 1580–1603, doi:10.3762/bjoc.19.116

• materials used in additive manufacturing. It is also compatible to a photopolymerization process. For example, it can be applied to the photo-3D-printing of silicone resin [83]. The refractive index is one of the most important optical properties and researchers have invested plenty of effort to develop

• refractive index from tetravinylsilane, ethanedithiol, and benzenedithiol. Polymers made by thiol–ene polymerization usually have well-ordered molecular networks. This character gives thiol–ene polymers highly tunable mechanical response hence it shows great application potential in additive manufacturing

• . Cook et al. [85] presented the first report of volumetric additive manufacturing-printed thiol–ene resins and showed the potential of the thiol–ene system. In addition to thiol–ene chemistry, radical hydrosilylation was also used to prepare linear, branched, or cross-linked polymers via a step-growth

Synthesis, α-mannosidase inhibition studies and molecular modeling of 1,4-imino-ᴅ-lyxitols and their C-5-altered N-arylalkyl derivatives

• Martin Kalník,
• Sergej Šesták,
• Juraj Kóňa,
• Maroš Bella and
• Monika Poláková

Beilstein J. Org. Chem. 2023, 19, 282–293, doi:10.3762/bjoc.19.24

• This work was supported by the Scientific Grant Agency of the Ministry of Education of Slovak Republic and Slovak Academy of Sciences (the projects VEGA-2/0010/23 and VEGA-2/0061/23), SAS Taiwan project (SAS-MOST/JRP/2019/882/GM-INHIB), the project implementation CEMBAM (Centre for Medical Bio-Additive

• Manufacturing and Research, ITMS2014+: 313011V358 supported by the Operational Programme Integrated Infrastructure funded by the European Regional Development Fund) and the Slovak Research and Development Agency (the project APVV-19-0376).

Cryogels: recent applications in 3D-bioprinting, injectable cryogels, drug delivery, and wound healing

• Luke O. Jones,
• Leah Williams,
• Tasmin Boam,
• Martin Kalmet,
• Chidubem Oguike and
• Fiona L. Hatton

Beilstein J. Org. Chem. 2021, 17, 2553–2569, doi:10.3762/bjoc.17.171

• adhesion. Cultivation and spreading of fibroblast NOR-10 cells were achieved within the cryogels, suggesting promise for tissue engineering applications. Building upon this work, hierarchical injectable cryogels were developed by Braschler and co-workers, based upon 3D additive manufacturing techniques [69

An initiator- and catalyst-free hydrogel coating process for 3D printed medical-grade poly(ε-caprolactone)

• Jochen Löblein,
• Thomas Lorson,
• Miriam Komma,
• Tobias Kielholz,
• Maike Windbergs,
• Paul D. Dalton and
• Robert Luxenhofer

Beilstein J. Org. Chem. 2021, 17, 2095–2101, doi:10.3762/bjoc.17.136

• Chemistry, Department of Chemistry and Helsinki Institute of Sustainability Science, Faculty of Science, University of Helsinki, 00014 Helsinki, Finland 10.3762/bjoc.17.136 Abstract Additive manufacturing or 3D printing as an umbrella term for various materials processing methods has distinct advantages

• fouling, critically depend mainly on the immediate surface energy. To gain control over the surface chemistry post-processing modifications are generally necessary, since it′s not a feature of additive manufacturing. Here, we report on the use of initiator and catalyst-free photografting and

• surface modification, we also observe bulk polymerization, which is expected for this method, and currently limits the controllability of this procedure. Keywords: additive manufacturing; light-induced polymerization; self-initiated photografting and photopolymerization; surface-initiated polymerization

Heterogeneous photocatalysis in flow chemical reactors

• Christopher G. Thomson,
• Ai-Lan Lee and
• Filipe Vilela

Beilstein J. Org. Chem. 2020, 16, 1495–1549, doi:10.3762/bjoc.16.125

Low-budget 3D-printed equipment for continuous flow reactions

• Jochen M. Neumaier,
• Amiera Madani,
• Thomas Klein and
• Thomas Ziegler

Beilstein J. Org. Chem. 2019, 15, 558–566, doi:10.3762/bjoc.15.50

• ]. 3D-printing, also known as additive manufacturing, is a process, where the object is created layer by layer directly from the computer-aided design (CAD) model. There are different technologies available for printing continuous flow reaction devices like fused deposition modeling (FDM) [13][14

3D printed fluidics with embedded analytic functionality for automated reaction optimisation

• Andrew J. Capel,
• Andrew Wright,
• Matthew J. Harding,
• George W. Weaver,
• Yuqi Li,
• Russell A. Harris,
• Steve Edmondson,
• Ruth D. Goodridge and
• Steven D. R. Christie

Beilstein J. Org. Chem. 2017, 13, 111–119, doi:10.3762/bjoc.13.14

• School of Materials, The University of Manchester, Manchester, M13 9PL, UK Faculty of Engineering, The University of Nottingham, Nottingham, NG7 2RD, UK 10.3762/bjoc.13.14 Abstract Additive manufacturing or ‘3D printing’ is being developed as a novel manufacturing process for the production of bespoke

• micro- and milliscale fluidic devices. When coupled with online monitoring and optimisation software, this offers an advanced, customised method for performing automated chemical synthesis. This paper reports the use of two additive manufacturing processes, stereolithography and selective laser melting

• reaction analysis; reaction optimisation; selective laser melting; stereolithography; Introduction Additive manufacturing (AM), or as it is widely known ‘3D printing’, is the internationally recognised term used to describe a wide range of manufacturing processes that can generate complex three

3D-printed devices for continuous-flow organic chemistry

• Vincenza Dragone,
• Victor Sans,
• Mali H. Rosnes,
• Philip J. Kitson and
• Leroy Cronin

Beilstein J. Org. Chem. 2013, 9, 951–959, doi:10.3762/bjoc.9.109

• , understanding the kinetics of the processes can allow the (re-)designing of the reactionware, allowing us to combine additional kinetic knowledge with reactor designs. Moreover, the additive manufacturing process of the devices takes a short time and results in a cheap procedure for the fabrication of fluidic